Lithium Compounds

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Product name

CAS

Formula

Lithium Hydroxide, Anhydrous

CAS1310-65-2

FormulaLiOH

SynonymLithium hydrate, Lithium hydroxide anhydrous, Lithium hydroxide (Li(OH)), Lithium hydroxide

Density1.5

Slightly Solublein alcohol

Moderately Solublein water forming strongly alkaline solns.

Melting Point462C

Assaytypical 98.5%

Altypical 0.04%

CO2typical 0.8%

Solubility11.4 g/100g water at 40C

Solubility12.0 g/100g water at 60C

Solution enthalpy20.4 kJ/mol in water

Appearencewhite, fine crystalline material

Molecular weight1.43 g/ccm at 20C

Solubility11.3 g/100g water at 20C

Bulk Density0.4 - 0.5 g/ccm

Theoretical lithium content29%

Specific Heat2.07 J•g-1•K-1

Grain sizeabout 90% 0.05-0.5 mm

Na + Ktypical 0.08%

Mgtypical 0.001%

Fetypical 0.001%

Cltypical 0.02%

SO4typical 0.02%

Solubility13.3 g/100g water at 80C

Solubility15.0 g/100g water at 100C

Odorodorless

Colorwhite powder or colorless crystal

Boiling Pointdec. 924 c

Lithium Hydroxide Monohydrate

CAS1310-66-3

FormulaH3LiO2

Synonymlithium hydroxide hydrate

Slightly Solublein alcohol

Moderately Solublein water

Assay> 56.5%

Molecular weight41.96 g/mol

Solubility21.6 g/100g water at 20C

Solution enthalpy3.6 kJ/mol in water

Fe2O3< 0.001%

Water Insolubles< 0.1%

Na + K< 0.3%

CO2< 0.35%

SO4< 0.05%

Cl< 0.05%

Melting Point462C for LiOH

Solubility22.0 g/100g water at 40C

Solubility29.6 g/100g water at 100C

Appearencewhite, yellowing, fine crystalline powder

Density1.51 g/ccm at 20C

Grain size0.1-1.0 mm

Bulk Densityabout 0.8 g/ccm

Solubility23.1 g/100g water at 60C

Solubility25.6 g/100g water at 80C

pH14 (1 aq. soln.)nonflamm.

Insolubilityin ether

Odorodorless

Colorcolorless crystal

Specific gravity1.51

Lithium Citrate

CAS6080-58-6

FormulaC6H7LiO7.4H2O

Synonymlithium 3-carboxy-3,5-dihydroxy-5-oxopentanoate

Transition range100-150C (due to dehydration)

Cl< 0.01%

Insolubles< 0.005% in water

Assay> 99% (dry substance)

Ca< 0.01%

Mg< 0.01%

Fe< 0.001%

SO4< 0.01%

H2O24-28%

Appearencewhite powder

Solubility74.5 g/100g water at 25C

Bulk Density0.8 - 0.9 g/ccm

Theoretical lithium content7.38%

Na< 0.05%

Heavy Metals< 0.002% as Pb

K< 0.05%

Molecular weight281.98

Lithium Fluoride

CAS7789-24-4

FormulaLiF

SynonymFluorolithium, Lithium monofluoride, Lithium fluoride (LiF)

Slightly Solublein water

Melting Point870C

Catypical 0.04%

Mgtypical 0.01%

Cltypical 0.01%

Ktypical 0.02%

Fetypical 0.01%

Co3typical 0.1%

LOl (200C)typical 0.3%

Natypical 0.02%

SO4typical 0.05%

PO4typical 0.01%

Appearencewhite, crystalline powder

Density2.6 g/ccm at 20C

Solubility0.29 g/100g water at 20C

Molecular weight25.94

Boiling Point1681C

Assaytypical 98.5%

Bulk Densityca. 0.4 g/ccm

Insolubilityin alcohol

Lithium Chromate

CAS14307-35-8

FormulaLi2CrO4

Synonymdilithium dioxido(dioxo)chromium, Dilithium chromate, Chromium lithium oxide, Chromic acid, dilithium salt, Chromic acid (H2CrO4), lithium salt (1:2)

Appearenceclear yellow odourless solution

Assay36.0 ± 1.0%

Insolubles< 0.01%

Ca< 0.20%

Solubility94.6 g/l at 20C

SO4< 0.20%

Density1.35 ± 1.0% g/ccm at 20C

Cl< 0.20%

Mg< 0.020%

pH7-10, 10% solution

Melting Point74.6 c (dec.)

Molecular weight129.88

Lithium Chloride

CAS7447-41-8

FormulaLiCl

SynonymLithium Chloride Salt, Lithium chloride (LiCl), Lithium Chloride is the inorganic salt

Density2.068

Very Solublein water, alcohols, ether, pyridine, nitrobenzene

Ktypical 0.02%

Solution enthalpy+ 8370 cal at 15C

Solubility111.9 g/100g water at 80C

Assaytypical 99.5%

Catypical 0.007%

Fe + Altypical 0.001%

H2Otypical < 0.5% at 400C

Insolublestypical 0.003%

Solubility83.2 g/100g water at 20C

SO4typical 0.005%

Li2CO3typical 0.015%

Solubility89.8 g/100g water at 40C

Solubility98.4 g/100g water at 60C

Solubility128.3 g/100g water at 100C

Natypical 0.10%

Batypical 0.02%

Appearencewhite, crystalline granulate

Grain size90% between 0.1 and 1 mm

Bulk Densityabout 1 g/ccm

Specific gravity2.068 g/cm3

Molecular weight42.40

Boiling Point1382C

Melting Point614C

Vapor Pressure1 mm hg (547 c)

Refractive Index1.381

Lithium Bromide

CAS7550-35-8

FormulaLiBr

SynonymLithium monobromide, Lithium bromide (LiBr)

Slightly Solublein pyridine

Very Solublein water, alcohol, ether

Co3< 0.03%

Solubility191 g/100g H2O at 50C

Solubility232 g/100g H2O at 100C

Assay> 99.5%

Ca< 0.005%

Fe< 0.001%

Cu< 3 mg/kg

SO4< 0.01%

Molecular weight86.85

Density3.46 g/ccm at 20C

Melting Point547C

Solubility111 g/100g H2O at -20C

K< 0.03%

Mg< 0.002%

Solubility149 g/100g H2O at 20C

Na< 0.03%

Boiling Point1265C

Cl< 0.15%

H2O< 0.3% at 400C

pH6-12

Screenabout 90% 0.07-0.5 mm

Appearencewhite, crystalline powder

Boiling Point1265C

Bulk Densityabout 1.8 kg/l g/ccm

Solubility130 g/100g H2O at 0C

Insolubles< 0.005% in water

Odorodorless

Lithium Benzoate

CAS553-54-8

FormulaC7H5LiO2

SynonymBenzoic acid, lithium salt, Benzoic acid, lithium salt (1:1)

Solubility10 g/100 ml ethanol at 78C

Assay> 99%

Heavy Metals< 0.002% as Pb

Solubility40 g/100 ml water at 100C

Na< 0.05%

K< 0.05%

Cl< 0.05%

H2O< 0.5%

Molecular weight128.06

Appearencewhite powder

Bulk Densityca. 0.5 g/ccm

Theoretical lithium content5.42%

Fe< 0.001%

SO4< 0.05%

Solubility33 g/100 ml water at 25C

Solubility8 g/100 ml ethanol at 25C

Lithium Aluminate

CAS12003-67-7

FormulaLiAlO2

Synonymlithium oxido(oxo)alumane, Lithium metaaluminate, Aluminate (AlO21-), lithium (1:1)

Lithium Acetate

CAS546-89-4

FormulaC2H3LiO2

SynonymLithium ethanate, acetic acid, lithium salt, Acetic acid, lithium salt (1:1)

CH3COOLi> 99.0%

Na< 0.05%

Ca< 0.02%

H2O< 0.5% at 200C

Molecular weight65.99

Solubility40.8 g/100 g H2O at 20C

Solubility66.7 g/100 g H2O at 40C

Appearencewhite, crystalline powder

Density1.25 g/ccm @ 20C

Bulk Densityapprox 0.6 kg/l g/ccm

Melting Point280 - 285 C

Solubility93.8 g/100 g H2O at 50C

K< 0.01%

Cl< 0.01%

Heavy Metals< 0.002%

SO4< 0.02%

Fe< 0.001%

Methacrylic Acid, Lithium Salt

CAS13234-23-6

FormulaC3H4O2 . Li

SynonymLithium acrylate

8-Hydroxyquinolinolato-lithium

CAS850918-68-2

FormulaC9H6LiNO

SynonymLiq, 8-Hydroxyquinolinolato-lithium

Lithium Hexafluorophosphate

CAS21324-40-3

FormulaLiPF6

Synonymlithium (methyl{(3R)-3-phenyl-3-[4-(trifluoromethyl)phenoxy]propyl}amino)acetate, Phosphate(1-), hexafluoro-, lithium (1:1)

AppearanceWhite crystal.

Moisture20ppm max

Content99.9% min

Molecular weight151.98 g/mol

Free Acid100ppm max

Lithium Nitrate

CAS7790-69-4

FormulaLiNO3 (in H2O)

Synonymlithium nitrate, Nitric acid, lithium salt (1:1)

Catypical 0.15%

Molecular weight68.95

Density2.37 g/ccm at 20C

Bulk Densityapprox. 1.13 g/ccm

Decomposition temperature> 600C

Fetypical <0.001%

Cltypical 0.05%

Melting Point251C

Natypical 0.15%

Appearencewhite, hygroscopic crystals

Assaytypical 99.3%

Ktypical 0.05%

Altypical <0.001%

Co3typical <0.05%

SO4typical 0.25%

H2Otypical 0.1%

Colorcolorless powder

Solubilitywater, alcohol

Lithium Aspartate 4% 40M

FormulaC45H69NO8

Synonym2,3-bis(dodecyloxy)propyl 4-methyl-3-oxo-3H-phenoxazin-7-yl pentanedioate

Li Content4.0%-5.0%

pHTo be determined

ColorTo be determined

Loss on DryingNot More Than 5%

Leadless than 1 ppm

Arsenicless than 1 ppm

Mercuryless than 1 ppm

E.ColiNegative

ColiformNegative

SalmonellaNegative

StaphylococcusNegative

Total Plate CountLess Than 3000/gm

Yeast & MoldsLess Than 300/gm

Lithium Orotate

CAS5266-20-6

FormulaC5H3LiN2O4

Synonymlithium 2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylate, 4-Pyrimidinecarboxylic acid, 1,2,3,6-tetrahydro-2,6-dioxo-, lithium salt (1:1)

Li Content1.0%-1.5%

pHTo be determined

ColorTo be determined

Loss on DryingNot More Than 5%

Leadless than 1 ppm

Arsenicless than 1 ppm

Mercuryless than 1 ppm

E.ColiNegative

ColiformNegative

SalmonellaNegative

StaphylococcusNegative

Total Plate CountLess Than 3000/gm

Yeast & MoldsLess Than 300/gm

Lithium Carbonate

CAS554-13-2

FormulaLi2CO3

SynonymDilithium Carbonate, Dilithium Salt, Carbonic Acid, Carbonic acid, lithium salt (1:2), LITHIUM CARBONATE

Practically Insolublein ethanol

Slightly Solubleod. sol. in water

Ba< 0.0005%

Melting Point32C

As< 0.0002%

Bulk Densityabout 0.5 kg/l g/ccm

Solubility1.54 g/100g water at 0C

K< 0.0002%

Cl< 0.0005%

H2O< 0.4%

Heavy Metals0.0005% as Pb

SO4< 0.01%

Appearencewhite, fine-grained powder

Appearence73.89

Density2.11 g/ccm at 20C

Screen95% < 0.1 mm

Solubility1.17 g/100g water at 40C

Solubility1.01 g/100g water at 60C

Solubility0.72 g/100g water at 100C

Ca< 0.0005%

Al< 0.0005%

Solubility1.33 g/100g water at 20C

Solubility0.85 g/100g water at 80C

Assay> 99.9%

Na< 0.0005%

Fe< 0.0005%

Mg< 0.0005%

pH11.2

Insolubilityin acetone, ammonia

Molecular weight73.89

Boiling Pointdec. 726 c

Lithium Chelate 0.2%, 40M

CAS7790-28-5

FormulaC45H69NO8

Synonym2,3-bis(dodecyloxy)propyl 4-methyl-3-oxo-3H-phenoxazin-7-yl pentanedioate, Periodic acid (HIO4), sodium salt (1:1)

Density3.865 (16 c)

Direct Evaporative Coolingon heating with o2 evolution

Very Solublein water

Colorcolorless crystal

Melting Point300 c (dec.)

Molecular weight213.89

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