Lithium Compounds

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Formula

Lithium Orthosilicate

CAS13453-84-4

FormulaLi4O6Si2

Synonymtetralithium dioxido(oxo)silane, Tetralithium silicate, Silicic acid (H4SiO4), lithium salt (1:4)

Solubilitydecomposition in boiling water

Natypical 0.2%

Loss on Dryingtypical 0.03% at 200C

Molecular weight105.97

Density2.4 g/ccm at 20C

Assaytypical 97.5%

Grain size< 350 um

CO2typical 0.5%

Appearencewhite, crystalline powder

Ktypical 0.4%

SO4typical 0.06%

Solubilityinsoluble in water at 20C

Lithium Carbonate

CAS554-13-2

FormulaLi2CO3

SynonymDilithium Carbonate, Dilithium Salt, Carbonic Acid, Carbonic acid, lithium salt (1:2), LITHIUM CARBONATE

Practically Insolublein ethanol

Slightly Solubleod. sol. in water

Ba< 0.0005%

Melting Point32C

As< 0.0002%

Bulk Densityabout 0.5 kg/l g/ccm

Solubility1.54 g/100g water at 0C

K< 0.0002%

Cl< 0.0005%

H2O< 0.4%

Heavy Metals0.0005% as Pb

SO4< 0.01%

Appearencewhite, fine-grained powder

Appearence73.89

Density2.11 g/ccm at 20C

Screen95% < 0.1 mm

Solubility1.17 g/100g water at 40C

Solubility1.01 g/100g water at 60C

Solubility0.72 g/100g water at 100C

Ca< 0.0005%

Al< 0.0005%

Solubility1.33 g/100g water at 20C

Solubility0.85 g/100g water at 80C

Assay> 99.9%

Na< 0.0005%

Fe< 0.0005%

Mg< 0.0005%

pH11.2

Insolubilityin acetone, ammonia

Molecular weight73.89

Boiling Pointdec. 726 c

Lithium Iodide Trihydrate

CAS7790-22-9

FormulaH6ILiO3

SynonymLITHIUM IODIDE, HYDROUS, LITHIUM IODIDE REAGENT, LithiuM iodide (LiI),trihydrate (9CI), LITHIUM IODIDE TRIHYDRATE, LITHIUM IODIDE, LITHIUM IODIDE HYDRATE, LITHIUM IODIDE, HYDRATED (3H2O)

Molecular weight187.89

Boiling Point1171 °C

Density3.49

Melting Point73 °C

Lithium hexamethyldisilazane

CAS4039-32-1

FormulaLiN[Si(CH3)3]2

Synonym[dimethyl-(trimethylsilylamino)silyl]methane, LHMDS, Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, lithium salt (1:1)

Appearencewhite to off-white crystals

Assay93% min

Molecular weight167.33

Bulk Density0.437 g/ccm

Lithium Di-isopropylamide

CAS4111-54-0

FormulaC6H14LiN

SynonymLDA, Lithium Diisopropylamide, N-propan-2-ylpropan-2-amine, 2-Propanamine, N-(1-methylethyl)-, lithium salt (1:1)

Molecular weight107.13

Appearencelight yellow to red brown solution

Density0.80 g/ccm at 20C

Lithiumamide

CAS7782-89-0

FormulaLiNH2

SynonymLithium Amide, lithium azanide, Lithium amide (Li(NH2))

Appearencewhite to grey fine powder

Molecular weight22.96

Assay94% min

Density1.18 g/ccm at 20C

Bulk Densityabout 0.6 g/ccm

Melting Point380-400C

Particle Sizetypical 90% < 0.4 mm

LiH6% max

Solubilityunsoluble in common solvents, except for liquid ammonia

Lithium tert-butoxide

CAS1907-33-1

FormulaC4H9LiO

Synonymlithium 2-methylpropan-2-olate, tert-Butoxylithium, 2-Propanol, 2-methyl-, lithium salt (1:1)

Appearencewhite to off-white powder

Solubility13% w/w in Heptane at 20C

Assay99% min

Solubility5% w/w in toluene at 20C

Molecular weight80.06

Bulk Densityabout 0.5 g/ccm

Melting Pointabout 283C

Solubility2% w/w in tert-Butanol at 20C

Solubility23% w/w in THF at 20C

LiOH + Li2CO31% max as LiOH

Lithium Methoxide

CAS865-34-9

FormulaCH3-OLi

SynonymLIOME, lithium methanolate, Methanol, lithium salt (1:1)

Molecular weight37.98

Solubility14.4% w/w methanol at 20C

Bulk Density0.60 g/ccm

Assay99% min

LiOH + Li2CO31% max as LiOH

Appearencewhite, crystalline powder

Lithium iso-propoxide

CAS2388-10-5

FormulaC3H7LiO

SynonymLithium Isopropoxide

Solubility36 % w/w in MTBE at 20C

Solubility33% w/w in THF at 20C

Solubility42% w/w in methylcyclohexane at 20C

Solubility42% w/w in heptane at 20C

LiOH + Li2CO31.2% max

Molecular weight66.03

Bulk Densityabout 0.6 g/ccm

Melting Point> 280C

Solubility41% w/w in hexane at 20C

Appearencewhite powder

Assay98% min

Solubility24% w/w in toluene at 20C

Lithium Borohydride

CAS16949-15-8

FormulaLiBH4

SynonymLithium tetrahydroborate, lithium boron(1-), Borate(1-), tetrahydro-, lithium (1:1)

Appearencecolorless, slightly turbid solution

Molecular weight21.78

Density0.89 g/ccm at 20C

Vapor Pressureof solution, 200 mbar at 20C

Assay9.5-10.5%

Boiling Point66C for THF

Flash Point-20C for THF

Lithium tert-Amoxide

CAS53535-81-2

FormulaC5H11LiO

SynonymLTA, Lithium t-amoxide

Appearencecolorless to slightly yellow solution

Density0.74 g/ccm at 20C

Assay39-41%

Molecular weight94.08

Boiling Point90-100C for heptane

LiOH + Li2CO30.5% max as LiOH

Lithium Tri-Ethyl Borohydride

CAS22560-16-3

FormulaLi(C2H5)3BH

SynonymLithium Triethylborohydride

Boiling Point66C for THF

Flash Point-21.5C for THF

Appearencecolorless liquid

Molecular weight105.94

Assaytypical 20%

Density0.89 g/ccm at 20C

Lithium Hydride

CAS7580-67-8

FormulaLiH

SynonymLithium monohydride, Lithium hydride (LiH)

Reactivitywith water

Very Solublein acid

H2 equilibrium pressure850C: about 1010 mbar

Na0.9% max

K0.05% max

Appearencebluish grey grains

Density0.78 g/ccm at 20C

Molecular weight7.95

Bulk Densityabout 0.4 kg/l

Melting Point688C

Hydrogen content12.7% theoretical

Heat of fusionabout 2.5 kJ/g

Decomposition temperatureabove 900C

H2 equilibrium pressure500C: 0.09 mbar

Assay97.0% min

Insolubilityin benzene, toluene

Odorodorless

Solubilityether

Boiling Pointdec. 850 c

Lithium tri(tert-butoxy)aluminum hydride

CAS17476-04-9

FormulaC12H28AlLiO3

SynonymLTTBA, Lithium aluminumtri-tert-butoxyhydride, Lithium aluminum tri-tert-butoxyhydride, Aluminate(1-), hydrotris(2-methyl-2-propanolato)-, lithium (1:1), (T-4)-

Slightly Solublein other ethers

Appearencewhite to slight grey powder

Assay95-100%

Molecular weight254.28

Bulk Densityabout 0.5 g/ccm

Solubilitydiethylene glycol dimethyl ether, tetrahydrofuran

Lithium Aluminum Hydride

CAS16853-85-3

FormulaLiAIH4

Synonymlithium alumanuide, Lithium aluminohydride, Lithium tetrahydridoaluminate, Lithium tetrahydroaluminate, LAH, Aluminate(1-), tetrahydro-, lithium (1:1), (T-4)-

Appearencewhite to light grey powder

Bulk Densityabout 0.4 g/ccm

Molecular weight37.95

Density0.9 g/ccm at 20C

Theoretical hydrogen content10.62% equivalent to 2.36 lithers of hydrogen per g evolved in hydrolysis

Solubilityabout 39 g/100g diethyl ether

Solubilityabout 0.1 g/100g dioxane

Decomposition temperatureappreciable decomposition with evolution of hydrogen at 125C and above

Solubilityabout 15 g/100g tetrahydrofuran

Solubilityabout 2 g/100g of dibutyl ether

Assay97% min

Lithium Tetraborate

CAS12007-60-2

FormulaLi2B4O7

SynonymLithium borate, Dilithium tetraborate, Boron lithium oxide, Boron lithium oxide (B4Li2O7)

Bulk Densityabout 0.3 g/ccm

Appearencewhite powder

Melting Point760-910C

Na2Otypical 0.027%

Al2O3typical 0.02%

SiO2typical 0.05%

Specific gravity2.4 g/ccm

Max of endothermic fusion890C

Assaytypical 99.3%

MgOtypical 0.017%

CaOtypical 0.014%

Fe2O3typical 0.013%

Molecular weight169.12

Grain size< 250 um

Lithium Sulfate Anhydrous

CAS10377-48-7

FormulaLi2SO4

Synonymdilithium sulfate, Lithium sulphate, Sulfuric acid, dilithium salt, Sulfuric acid, lithium salt (1:2)

Molecular weight109.94

Density2.22 g/ccm at 20C

Assaytypical 99.0%

Natypical 0.08%

Ktypical 0.08%

Fetypical 0.0007%

Cltypical 0.04%

Heavy Metalstypical < 0.002% as Pb

Appearencewhite, crystalline powder

Grain size90% < 0.15 mm

H2Otypical 0.25% at 110C

Catypical 0.012%

Mgtypical 0.004%

Melting Point860C

Lithium Succinate

CAS16090-09-8

FormulaLiOOC-CH2-CH2-COOLi

Synonymlithium 4-hydroxy-4-oxobutanoate

Appearencewhite powder

Cl< 0.01%

H2O< 0.5%

Molecular weight129.96

Solubility29 g/100g water

Assay> 98%

Na< 0.05%

Fe< 0.002%

Heavy Metals< 0.002% as Pb

SO4< 0.05%

K< 0.05%

Lithium Phosphate

CAS10377-52-3

FormulaLi3PO4

Synonymtrilithium phosphate, Trilithium orthophosphate, Phosphoric acid, trilithium salt, Phosphoric acid, lithium salt (1:3)

Appearencewhite, crystalline powder

Density2.54 g/ccm at 20C

Grain size80% < 0.1 mm

Bulk Densityapprox. 0.8 g/ccm

Melting Pointapprox. 1150C

Assaytypical 91%

Natypical 0.4%

Ktypical 0.01%

Catypical 0.02%

Altypical 0.02%

Co3typical 0.05%

Cltypical 0.01%

Fetypical 0.006%

SO4typical 0.01%

Molecular weight115.8

Lithium Peroxide

CAS12031-80-0

FormulaLi2O2

Synonymdilithium peroxide, Lithium peroxide (Li2(O2))

Grain sizetyp. < 100 um

Bulk Density0.35 g/ccm

Molecular weight45.88

Appearencewhite to pale yellow powder

Density2.3 g/ccm at 20C

Assaytyp. 96%

Active Oxygen34.9%

Heat of solvation30.1 kJ/mol at 20C

Lithium Perchlorate

CAS7791-03-9

FormulaLiClO4

SynonymPerchloric acid, lithium salt, Perchloric acid, lithium salt (1:1)

Appearencewhite, crystalline powder

Molecular weight106.39

Bulk Density1.4 g/ccm

Melting Point236C

Assaytyp. >98.0%

Ktyp. 0.01%

Heavy Metalstyp < 0.005% as Pb

H2Otyp. 1%

Catyp. 0.005%

Natyp 0.01%

SO4typ 0.005%

Grain size90% 0.04 - 0.25 mm

Specific gravity2.428 g/ccm

Decomposition temperatureabout 430C

Cltyp. 0.005%

Lithium Nitrite, Solution

CAS13568-33-7

FormulaLiNO2

SynonymNitrous acid, lithium salt, Nitrous acid, lithium salt (1:1)

Lithium Nitride

CAS26134-62-3

FormulaLi3N

Synonymtrilithium nitride, Lithium nitride (Li3N)

Molecular weight34.82

Melting Point845C

Appearencefine red-brown powder

Assaymin. 94%

Density1.38 g/ccm

Theoretical lithium content59.8%

Lithium Metaborate

CAS13453-69-5

FormulaLiBO2

Synonym-, Boric acid (HBO2), lithium salt (1:1)

Mg< 0.01%

Molecular weight49.75

Density1.4 g/ccm at 20C

Melting Point760C

Na< 0.01%

K< 0.005%

SiO2< 0.1%

Fe< 0.005%

Grain size< 250 um

SO4< 0.01%

Appearencewhite powder

Bulk Densityabout 0.49 g/ccm

Assay> 99.0%

Ca< 0.02%

Lithium Metasilicate

CAS1010-224-6

FormulaLi2SiO3

Synonym-

Appearencewhite powder

Solubility0.06 g/100g water at 70C

Assay96.0% min

Natypical 0.2%

CO2typical 0.5%

SO4typical 0.02%

Density2.52 g/ccm at 20C

Bulk Density0.8-0.9 g/ccm

Ktypical 0.4%

Loss on Drying1.0% max at 200C

Molecular weight89.97

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